Excited-state relaxation in PbSe quantum dots

In solids the phonon-assisted, nonradiative decay from high-energy electronic excited states to low-energy electronic excited states is picosecond fast. It was hoped that electron and hole relaxation could be slowed down in quantum dots, due to the unavailability of phonons energy matched to the large energy-level spacings (“phonon-bottleneck”). However, excited-state relaxation was observed to be rather fast (1 ps) in InP, CdSe, and ZnO dots, and explained by an efficient Auger mechanism, whereby the excess energy of electrons is nonradiatively transferred to holes, which can then rapidly decay by phonon emission, by virtue of the densely spaced valence-band levels. The recent emergence of PbSe as a novel quantum-dot material has rekindled the hope for a slow down of excited-state relaxation because hole relaxation was deemed to be ineffective on account of the widely spaced hole levels. The assumption of sparse hole energy levels in PbSe was based on an effective-mass argument based on the light effective mass of the hole. Surprisingly, fast intraband relaxation times of 1–7 ps were observed in PbSe quantum dots and have been considered contradictory with the Auger cooling mechanism because of the assumed sparsity of the hole energy levels. Our pseudopotential calculations, however, do not support the scenario of sparse hole levels in PbSe: Because of the existence of three valence-band maxima in the bulk PbSe band structure, hole energy levels are densely spaced, in contradiction with simple effective-mass models. The remaining question is whether the Auger decay channel is sufficiently fast to account for the fast intraband relaxation. Using the atomistic pseudopotential wave functions of Pb2046Se2117 and Pb260Se249 quantum dots, we explicitly calculated the electron-hole Coulomb integrals and the PS electron Auger relaxation rate. We find that the Auger mechanism can explain the experimentally observed PS intraband decay time scale without the need to invoke any exotic relaxation mechanisms

Nonlinear Kinetic Dynamics of Magnetized Weibel Instability

Kinetic numerical simulations of the evolution of the Weibel instability during the full nonlinear regime are presented. The formation of strong distortions in the electron distribution function resulting in formation of strong peaks in it and their influence on the resulting electrostatic waves are shown.Comment: 6 pages, 4 figure

Fast growing instabilities for non-parallel flows

Unstable modes growing when two plasma shells cross over a background plasma at arbitrary angle $\theta$, are investigated using a non-relativistic three cold fluids model. Parallel flows with $\theta=0$ are slightly more unstable than anti-parallel ones with $\theta=\pi$. The case $\theta=\pi/2$ is as unstable as the $\theta=0$ one, but the fastest growing modes are oblique. While the most unstable wave vector varies with orientation, its growth rate slightly evolves and there is no such thing as a stable configuration. A number of exact results can be derived, especially for the $\theta=\pi/2$ case.Comment: 4 pages, 3 figures, to appear in Phys. Lett.

Unfinished Business

The following is excerpted from an address given by HEW Secretary Joseph A. Califano, Jr., at the 111 th Convocation of Howard University, September 22, 1978